화학과학의 원리

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화학과학의 원리

MIT
Prof. Catherine Drennan,Dr. Elizabeth Vogel Taylor

페이스북 트위터 카카오톡 네이버밴드 링크복사

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자연과학 >생물ㆍ화학ㆍ환경 >생화학
등록일자

2009.08.05

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18,658

This course provides an introduction to the chemistry of biological, inorganic, and organic molecules. The emphasis is on basic principles of atomic and molecular electronic structure, thermodynamics, acid-base and redox equilibria, chemical kinetics, and catalysis.

차시별 강의

1.	파동 -입자 이원성, 슈뢰딩거 방정식
2.	화학 원리의 중요성	1. An introduction to chemistry 2. General course information and policies for 5.111 3. Introduction of teaching staff
3.	전자와 핵의 발견과 양자역학의 필요성	1. Discovery of electron and the nucleus 2. (Failure of) the classical description of the atom 3. An introduction to quantum mechanics
4.	파동-빛의 분자 이중성	1. (Failure of) the classical description of the atom 2. Introduction to quantum mechanics: wave-particle duality 3. Light as a wave: characteristics of waves 4. Light as a particle: the photoelctric effect
5.	수소원자 에너지 레벨	The Hydrogen Atom 1. Binding energy of the electron to the nucleus 2. Verification of hydrogen-atom energy levels A. Photon emission B. Photon absorption 3. Wavefunctions (orbitals) for the hydrogen atom
6.	수소원자 파동함수(오비탈)	Hydrogen Atom Wavefunctions 1. Wavefunctions (orbitals) for the hydrogen atom 2. shapes of H-atom wavefunctions: s orbitals 3. Radial probability distributions
7.	p-오비탈	The Hydrogen Atom 1. Radial probability distributions for s-orbitals 2. p-orbitals A. The shape of p-orbitals B. Radial probability distributions Multi-electron Atoms 3. Electron spin 4. Wavefunctions for multielectron atoms
8.	다전자원자와 전자 배열	Multi-electron Atoms 1. Wavefunctions for multi-electron atoms 2. Binding energy 3. Electron configurations(Aufbau principle) 4. Photoelectric spectroscopy
9.	주기율 경향	1. Photoelectric spectroscopy 2. Periodic table/ periodic trends A. Ionization energy B. Electron affinity C. Electronegativity D. Atomin rsdius 3. Isoelectronic atomes/ions
10.	주기율 경향 계속 : 공유 결합	Finish exam 1 material: 1.Atomin rsdius and Isoelectronic atomes/ions Exam 2 material: 2. Covalent bonds 3. Lewis structures
11.	루이스 구조식	Lewis structures
12.	루이스 구조식 법칙의 예외 : 이온 결합	1. Breakdown of the octet rule case1. Odd number of valence electrons case2. Octet deficient molecules case3. Valence shell expansion 2. Iinic bonds 3. Polar covalent bonds
13.	극성 공유 결합: VSEPR 이론	1. Polar covalent bonds and polar molecules 2. The shapes of molecules: VESPR theory A. Molecules without lone pairs B. Molecules with lone pairs
14.	분자 오비탈 이론	Molecules orbital theory 1. Bonding and antibonding orbitals 2. Homoneclear diaomic molecules A. Molecules with MO's originating from a orbitals B. Molecules with MO's originating from a and p orbitals 3. Heteronuclear diatomic molecules
15.	원자가 결합 이론과 교잡	Molecules orbital theory Valence bond theory and hybridization 1. Sigma and pi bonds 2. Hybridization of atomic orbitals 3. Hybridization in complex molecules
16.	복합분자의 교잡 측정: 열화학 과 결합 에너지/ 결합 엔탈피	1.Valence bond theory and hybridization Determining hybrization in complex molecules 2.Energies and enthalpies of chemical reaction A. Bond energy/ bond enthalpy B. Heat of formation
17.	엔트로피와 무질서	Thermodynamics 1. Enthalpies of chemical reactions 2. Spontaneous change and free energy 3. Entropy 4. Free energy of formation
18.	자유에너지와 자발성의 억제	Thermodynamics 1. Free energy do formation 2. Effect of temperature on spontaneity 3. Thermodynamics in biological systems A) ATP-coupled reactions B) Hydrogen bonding
19.	화학 평형	Nature of Chemical Equilibrium Meaning of K Relationshil between Equilibrium Expressions External effects on K
20.	르 샤틀리에의 원리와 혈액에 산소 레벨의 적용	Changing the volume
21.	산-염기 평형: MIT물은 마시기에 안전한가?	Classification of Acid-Bases, Autoionization of Water, pH Function, Strength of Acids and Bases, Equilibrium Involving Weak Acids.
22.	화학과 생물학의 완충기	Equilibrium involving weak bases, pH of salt solutions, and buffers
23.	산-염기 적정	Topic: Titrations
24.	산화/환원	Topics: Oxidation States, and Balancing Oxidation/Reduction Reactions (Read Section K)
25.	전기화학적 세포	Topics:Electrochemical Cells, Faraday's Law, and the Relationship between Gibbs Free Energy and Cell Potential
26.	화학과 생물학적 산화/ 환원	Topics: Adding and Subtracting Half-Cell Reactions and Nernst Equation
27.	전이와 납중독 처리	Topics: Formation of coordination complexes, coordination number, coordination complex notation, structures of coordination complexes, chelate effect, isomers, d- electron counting, and d-orbitals.
28.	결정 전기장 이론	Crystal field and ligand field theories
29.	생물학에의 금속	Crystal Field Theory Continued, and Magnetism
30.	자성과 분광화학의 이론	Crystal Field Theory and the Spectrochemical Series.
31.	비율 법칙	Rates of Chemical Reactions and Rate Law
32.	핵 화학과 핵 반응	Radioactive Decay, Second Order Integrated Rate Laws, Kinetics and Chemical Equilibrium, Introduction to Reaction Mechanisms
33.	반응 메카니즘	Reaction Mechanisms
34.	온도와 동역학	Effect of Temperature, Collision Theory, Activated Complex Theory.
35.	효소 촉매작용	Topic: Catalysis
36.	생화학	Review of Topics : Chemical Equilibrium, Acid Base, Oxidation Reduction, Transition Metals, and Kinetics