1. | 분광 실질 해밀토니안 개론 | The Born-Oppenheimer approximation and matrix elements of terms in the effective molecular Hamiltonian that violate the BO approximation. Vibration, rotation, spin-orbit, interelectronic interaction. Hund's coupling cases. | ||
2. | 분광 섭동, 유발분해, 자동이온화 | Introduction to dynamical processes. | ||
3. | Vibrational Overlap Integrals 계산의 준 고전적인 방법 | All coupling processes are mediated by vibrational overlap integrals, which are computed numerically. Semiclassical calculation of overlaps reveals physical factors controlling computed values: the length of the stationary phase region is controlled by the slopes of the potential curves at the intersection and the velocity in the crossing region. | ||
4. | 파종묶음과 란다우-제너 | What happens in the vicinity of a curve crossing? |